Stability of the polyureas was higher than polyurethanes. Almost all polymers showed a T(g) around -50 degrees C. The mechanical properties of the polymers were determined by tensile tests. Among the polymers synthesized, castor oil polyurethane showed the highest elongation at break and the lowest tensile strength of 140 KPa. The highest tensile strength of 900 KPa was observed in the pentamethylene glycol polyurethanes. (C) 2010 Wiley Periodicals, Inc. LY411575 research buy J Appl Polym Sci 116: 2433-2440, 2010″
“We have examined the dependence of the magnetism from
perpendicular magnetic anisotropy with Co thickness in [Pt/Co] multilayers coupled to a NiO layer. We measure a perpendicular exchange bias field that changes polarity with Co thickness and find that with 2 nm of Co the perpendicular magnetic anisotropy is no longer present. Further evidence of the change in the S63845 nmr Co layers preferred orientation is offered by zero field cooled susceptometry, where the low temperature susceptibility is negative for thin Co layers (0.9-1.2 nm) and becomes positive with increasing Co thickness (1.5-2.0 nm). Thin Co layered
films also exhibit a compensation point around 100 K. These results indicate that the Co and NiO interface moments are coupled strongly and that there is competition between Pt/Co and Co/Ni at the film layer interfaces that sets the overall anisotropy from perpendicular and parallel configurations. (C) 2010 American Institute of Physics. [doi:10.1063/1.3340511]“
“Histidine-Tryptophan-Ketoglutarate (HTK) solution is increasingly used to flush and preserve organ donor kidneys, with efficacy claimed equivalent to University of Wisconsin (UW) solution. We observed and reported increased graft pancreatitis in pancreata flushed with HTK
solution, which prompted this review of transplanting HTK-flushed kidneys. We analyzed outcomes of deceased-donor kidneys flushed with HTK and UW solutions with a minimum of 12 months follow-up, excluding pediatric and multi-organ BGJ398 recipients. We evaluated patient and graft survival and rejection rates, variables that might constitute hazards to graft survival and renal function. Two-year patient survival, rejection, renal function and graft survival were not different, but early graft loss (< 6 months) was worse in HTK-flushed kidneys (p < 0.03). A Cox analysis of donor grade, cold ischemic time, panel reactive antibodies (PRA), donor race, first vs. repeat transplant, rejection and flush solution showed that only HTK use predicted early graft loss (p < 0.04; relative risk = 3.24), almost exclusively attributable to primary non-function (HTK, n = 5 (6.30%); UW, n = 1 (0.65%); p = 0.02). Delayed graft function and early graft loss with HTK occurred only in lesser grade kidneys, suggesting it should be used with caution in marginal donors.”
“A new aromatic diamine, viz.